如何让中空微球在水溶性聚氨酯或水溶性环氧树脂溶剂中形成较稳定的均匀悬浮液?
推荐回答(1个)
水性聚氨酯胶是指聚氨酯溶于水或分散于水中而形成的胶粘剂,有人也称水性聚氨酯胶为水系聚氨酯胶或水基聚氨酯胶。
水性聚氨酯胶依其外观和粒径,将其分为三类:聚氨酯水溶液(粒径<0.001um,外观透明)、聚氨酯分散液(粒径0.001-0.1 um,外观半透明)、聚氨酯乳液(粒径>0.1 ,外观白浊)。
水性聚氨酯胶最大的优势是以水为基本介质,具有不燃、气味小、不污染环境、节能、操作加工方便等优点,已受到人们的重视。
目前,水性聚氨酯的核心技术受技术壁垒而依旧被国外公司所控制,国内水性聚氨酯胶的价格成本较高,产品水平也参差不齐,比较好的唯有东方树脂生产的德力水性聚氨酯胶。
水性聚氨酯胶粘剂的性能特点与溶剂型聚氨酯胶粘剂相比,水性聚氨酯胶粘剂除了上述的无溶剂臭味、无污染等优点外,还具有下述特点。
(1)大多数水性聚氨酯胶粘剂中不含NCO基团,因而主要是靠分子内极性基团产生内聚力和粘附力进行固化。
而溶剂型或无溶剂单组分及双组分聚氨酯胶粘剂可充分利用NCO的反应、在粘接固化过程中增强粘接性能。
水性聚氨酯中含有羧基、羟基等基团,适宜条件下可参与反应,使胶粘剂产生交联。
(2)除了外加的高分子增稠剂外,影响水性聚氨酯粘度的重要因素还有离子电荷、核壳结构、乳液粒径等。
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聚合物分子上的离子及反离子(指溶液中的与聚氨酯主链、侧链中所含的离子基团极性相反的自由离子)越多,粘度越大;
而固体含量(浓度)、聚氨酯树脂的分子量、交联剂等因素对水性聚氨酯粘度的影响并不明显,这有利于聚氨酯的高分子量化,以提高胶粘剂的内聚强度。
与之相比,溶剂型聚氨酯胶粘剂的粘度的主要影响因素有聚氨酯的分子量、支化度、胶的浓度等。
相同的固体含量,水性胶粘剂的粘度较溶剂型胶粘剂小。
(3)粘度是胶粘剂使用性能的一个重要参数。
水性聚氨酯的粘度一般通过水溶性增稠剂及水来调整。
而溶剂型胶粘剂可通过提高固 含量、聚氨酯的分子量或选择适宜溶剂来调整。
(4)由于水的挥发性比有机溶剂差,故水性聚氨酯胶粘剂干燥较慢,并且由于水的表面张力大,对表面疏水性的基材的润湿能力差。
若当大部分水分还未从粘接层、涂层挥发到空气中,或者被多孔性基材吸收就遽然加热干燥,则不易得到连续性的胶层。
由于大多数水性聚氨酯胶是由含亲水性的聚氨酯为主要固体成分,且有时还含水溶性高分子增稠剂,胶膜干燥后若不形成一定程度的交联,则耐水性不佳。
(5)水性聚氨酯胶粘剂可与多种水性树脂混合,以改进性能或降低成本。
此时应注意离子型水性胶的离子性质和酸碱性,否则可能引起凝聚。
因受到聚合物间的相容性或在某些溶剂中的溶解性的影响,溶剂型聚氨酯胶粘剂只能与为数有限的其他树脂胶粘剂共混。
(6)水性聚氨酯胶粘剂气味小,操作方便,残胶易清理,而溶剂型聚氨酯胶粘剂使用中有时还需耗用大量溶剂,清理也不及水性胶方便。
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