常温下,将c mol⼀L 的醋酸溶液与0.02mol⼀L NaOH溶液等体积混合后,溶液刚好呈中性,用含c的代数式表示

CH3COOH的电离常数
2024-12-01 11:19:19
推荐回答(3个)
回答1:

CH3COOH+NaOH=CH3COONa+H2O
CH3COONa呈碱性,溶液刚好呈中性,所以醋酸要过量
剩余醋酸浓度c(CH3COOH)=(c-0.02)/2

电荷守恒:c(CH3COO-)+c(OH-)=c(Na+)+c(H+)
溶液呈中性,c(OH-)=c(H+)
所以c(CH3COO-)=c(Na+) =0.02/2=0.01(mol/L)

CH3COOH== CH3COO- + H+
平衡时 (c-0.02)/2 0.01 10^-7

K=c(CH3COO-)*c(H+)/c(CH3COOH)
=0.01*10^-7 / [(c-0.02)/2 ]
=2*10^-9/(c-0.02)

回答2:

Ka(HAc)=0.02*10^-7/(c-0.02)

回答3:

(c-0.0004)/(c-0.02)