推荐回答(5个)
1、苯环上的氢原子被卤素原子取代发生的反应叫亲电取代反应,例如:
![](/picurl?url=https%3A%2F%2Fiknow-pic.cdn.bcebos.com%2Fb8014a90f603738d1fea7f51b91bb051f819ec25%3Fx-bce-process%3Dimage%252Fresize%252Cm_lfit%252Cw_600%252Ch_800%252Climit_1%252Fquality%252Cq_85%252Fformat%252Cf_auto)
2、亲电取代反应机理:
![](/picurl?url=https%3A%2F%2Fiknow-pic.cdn.bcebos.com%2F377adab44aed2e73346cf45f8d01a18b87d6fa38%3Fx-bce-process%3Dimage%252Fresize%252Cm_lfit%252Cw_600%252Ch_800%252Climit_1%252Fquality%252Cq_85%252Fformat%252Cf_auto)
3、用氧化反应是不能达到目的的
当然是取代反应,卤素原子取代苯环上的氢原子,不会发生氧化反应,氧化还原反应是伴随着化合价的升降,而在有机中,只有消去、加成才会有化合价的变化(还有燃烧)。
苯环(phenyl ring)是一个闭合的共轭体系,六个碳原子的π电子云分布是一样的。但当苯环上有一个取代基时,取代基会改变苯环的电子分布,使分子极化。诱导效应和共轭效应都能产生这种分子极化。不仅使苯环的电子云密度增加或降低,而且还决定了苯环上各个位次电子云密度分布情况。
1.可以发生亲核取代反应(卤素变) 如卤苯在强碱条件下如NaNH2下回反应得到氨基苯
2.邻对位基团有强吸电子基团如-NO2
依旧符合定位效应的亲电取代反应,上邻对位
p.s.邻对位定位效应活性与间位定位效应
一.邻对位效应
1.强活化:伯氨基-NR2,仲氨基-NHR,氨基-NH2,羟基-OH 2.中等活化:酰胺基-NHCOR(碳氧双键),醚-OR, 羰基-OCOR(第二个是碳氧双键) 3.弱活化:烷基-R,苯基Ar, 4.弱钝化:卤代烷基-CH2X,卤原子-X
二.间位效应,钝化程度依次减弱:-N+R3,-NO2,-CF3,-CCI3,-CN,--SO3H,-CHO,-COR,-CO2H,-CO2R,-CONR2,
发生的是取代反应,本质上卤素原子的化学价降低,发生了还原反应,那相应的有机物发生的就是氧化反应。但在高中化学中卤代反应一般答取代反应,否则不得分。
苯环上的主要反应是亲电取代反应,这类反应是有一定的应用价值的,其次就是氧化反应,譬如工业上就是用苯的氧化来制备顺丁烯二酸酐,而对于加成反应没有一定的实际应用价值。所以当苯环上有卤素原子时,仍可发生取代反应,还可以在环上引入其它基团,如硝基、卤素、磺酸基等。
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