电感耦合等离子质谱工作原理

想知道质谱仪的简单工作原理 ?
2025-02-26 15:22:28
推荐回答(3个)
回答1:

质谱分析法主要是通过对样品的离子的质荷比的分析而实现对样品进行定性和定量的一种方法。因此,质谱仪都必须有电离装置把样品电离为离子,有质量分析装置把不同质荷比的离子分开,经检测器检测之后可以得到样品的质谱图,由于有机样品,无机样品和同位素样品等具有不同形态、性质和不同的分析要求,所以,所用的电离装置、质量分析装置和检测装置有所不同。但是,不管是哪种类型的质谱仪,其基本组成是相同的。都包括离子源、质量分析器、检测器和真空系统。本节主要介绍有机质谱仪的基本结构和工作原理。
9.2.1.1 离子源(Ion source)
离子源的作用是将欲分析样品电离,得到带有样品信息的离子。质谱仪的离子源种类很多,现将主要的离子源介绍如下。
电子电离源(Electron Ionization EI)
电子电离源又称EI源,是应用最为广泛的离子源,它主要用于挥发性样品的电离。图9.1是电子电离源的原理图,由GC或直接进样杆进入的样品,以气体形式进入离子源,由灯丝F发出的电子与样品分子发生碰撞使样品分子电离。一般情况下,灯丝F与接收极T之间的电压为70伏,所有的标准质谱图都是在70ev下做出的。在70ev电子碰撞作用下,有机物分子可能被打掉一个电子形成分子离子,也可能会发生化学键的断裂形成碎片离子。由分子离子可以确定化合物分子量,由碎片离子可以得到化合物的结构。对于一些不稳定的化合物,在70ev的电子轰击下很难得到分子离子。为了得到分子量,可以采用1020ev的电子能量,不过此时仪器灵敏度将大大降低,需要加大样品的进样量。而且,得到的质谱图不再是标准质谱图。
离子源中进行的电离过程是很复杂的过程,有专门的理论对这些过程进行解释和描述。在电子轰击下,样品分子可能有四种不同途径形成离子:
详细见资料:http://www.instrument.com.cn/bbs/shtml/20080825/1445727/

回答2:

ICP-MS是一种元素分析技术,这意味着它用于测量元素,而不是通过LC/MS和GC/MS测量的分子和化合物。ICP-MS使用氩(Ar)等离子体(ICP)将样品转化为离子,然后使用质谱仪进行测量。ICP-MS仪器由离子源(ICP)、质谱仪(MS)——通常是扫描四极质谱过滤器和检测器组成。ICP处于大气压力下,而MS和检测器在真空室中工作,因此ICP-MS还需要真空泵、真空接口和一些静电离子“透镜”来聚焦系统中的离子。现代ICP-MS系统通常还包含一些解决光谱干扰的设备或机制。一般分为单四极杆和串接四极杆,二者检出限和抗干扰能力不同.    

回答3:

电感耦合等离子体质谱也就是我们常说的icp--ms,属于无机质谱。他是用来检测样品里面的元素的微小含量,可以做到ppt。所以他属于分析检测工具。如果还不清楚的地方可以给我留言,希望能给你满意答复。

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