为什么若增加一种反应物的浓度,该反应物的转化率降低呢?```````
推荐回答(4个)
一个可逆反应。气体A+气体B<=>C+D
A的起始量一定时,增大B的起始量. 那么B的起始量越大,则每个B分子受到A分子碰撞的机率就越小。但是B的转化率与"单位时间内,单个B分子受到的有效碰撞次数成正比." 所以B的起始量越大,B的转化率就越低. 换个角度,B的起始量越大,则每个A碰撞到B的机率就越大,则A的转化率就越高.
这也就是说,提高哪种反应物的起始量,哪种反应物的转化率就会降低,而其他反应物的转化率就会升高.
一定温度下,生成物浓度的系数次方的乘积与反应物浓度系数次方的乘积之比为一常数
K值的大小,表示在一定温度下,反应达到平衡时该反应进行的程度,就是反应的限度.
K值越大,反应程度增大,转化率越高;反之则转化率越低.
转化率是 已反应的反应物的物质的量/反应物的总物质的量。所以当加入一种反应物时,平衡向正反应方向移动,其余反应物已反应的反应物的物质的量增加,反应物的总物质的量不变,所以转化率增大。而加入的反应物,即改变反应条件,由平衡移动原理(即化学平衡总是向减弱条件变化的方向移动)得,改变的条件只能减弱,不能抵消,所以已反应的反应物的物质的量、反应物的总物质的量同时增大,但反应物的总物质的量的增量大于已反应的反应物的物质的量的增量,所以转化率反而减小。根据勒夏特列原理,增加一种反应物的浓度,反应朝着能够减弱这种改变的反向移动,也就是向正反应方向移动。注意,是减弱,而不是完全抵消。即:添加的浓度完全是大于减弱的,该反应物的浓度还是增加了,所以转化率降低了。而另一种反应物,由于化学平衡正向移动,它转化率是增加的。
这个问题用"有效碰撞"理论来解释最为准确.
设可逆反应为:a(气)+b(气)+<====>c+d
固定a的起始量,增大b的起始量.
显然,b的起始量越大,则每个b分子受到a分子碰撞的机率就越小.(鸟群中的每只鸟,要比独飞的鸟受到鹰攻击的机率更小)
而b的转化率与"单位时间内,单个b分子受到的有效碰撞次数成正比."
故b的起始量越大,b的转化率就越低.
奇妙的是,如果转变看问题的角度,b的起始量越大,则每个a碰撞到b的机率就越大,则a的转化率就越高.(鹰向鸟群冲刺比向单只鸟冲刺更易碰到鸟.当然,前提是鹰不要被鸟群吓倒,嘿嘿.)
这也就是说,提高哪种反应物的起始量,哪种反应物的转化率就会降低,而其他反应物的转化率就会升高.
想象一下:浓度加大了,反应速率是被强行增快的。要想加大浓度就是要加入大量的原料,,也就是说原料加非常的多,而反应掉的只是增加一点。告诉你学理科是要想像的,不要老像老师说的那样计算个半死,那样考试时间不够的
按照楼主的举例,“增加一种反应物的浓度,该反应物的转化率降低”是指
当再加入1molB时,平衡向右进行,此时A的转化率增大,而加入的B最多转化了0.25mol(且达不到),故B转化率降低。
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