推荐回答(3个)
铁的电子构型为(Ar)3d64s2,氧化态有0、+2、+3、+4、+5、+6。铁的化学性质活泼,为强还原剂,在室温条件下可缓慢地从水中置换出氢,在500℃以上反应速率增高:
3Fe+4H2O(g)===Fe3O4+4H2↑
铁在干燥空气中很难与氧发生作用,但在潮湿空气中很易腐蚀,若含有酸性气或卤素蒸气时,腐蚀更快。铁可从溶液中还原金、铂、银、汞、铋、锡、镍或铜等离子,如:
CuSO4+Fe===FeSO4+Cu
铁溶于非氧化性的酸如盐酸和稀硫酸中,形成二价铁离子并放出氢气;在冷的稀硝酸中则形成二价铁离子和硝酸铵:
Fe+H2SO4===FeSO4+H2↑
4Fe+10HNO3===4Fe(NO3)2+NH4NO3+3H2O
铁溶于热的或较浓的硝酸中,生成硝酸铁并释放出氮的氧化物。在浓硝酸或冷的浓硫酸中,铁的表面形成一层氧化薄膜而被钝化。铁与氯在加热时反应剧烈(2Fe+3Cl2===2FeCl3)。铁也能与硫、磷、硅、碳直接化合。铁与氮不能直接化合,但与氨作用,形成氮化铁Fe2N。
铁的最重要的氧化态是+2和+3。二价铁离子呈淡绿色,在碱性溶液中易被氧化成三价铁离子。三价铁离子的颜色随水解程度的增大而由黄色经橙色变到棕色。纯净的三价铁离子为淡紫色。二价和三价铁均易与无机或有机配位体形成稳定的配位化合物,如 Phen为菲罗林,配位数通常为6。零价铁还可与一氧化碳形成各种羰基铁,如Fe(CO)5、Fe2(CO)9、Fe3(CO)12。羰基铁有挥发性,蒸气剧毒。铁也有+4、+5、+6价态的化合物,但在水溶液中只有+6价的。
化合物 主要有两大类:亚铁Fe(Ⅱ)和正铁Fe(Ⅲ)化合物,亚铁化合物有氧化亚铁(FeO)、氯化亚铁(FeCl2)、硫酸亚铁(FeSO4)、氢氧化亚铁{Fe(OH)2}等;正铁化合物有三氧化二铁(Fe2O3)、三氯化铁(FeCl3)、硫酸铁{Fe2(SO4)3}、氢氧化铁{Fe(OH)3}等。
如在亚铁氰化钾K4[Fe(CN)6]·3H2O(俗名:黄血盐)和铁氰化钾K3[Fe(CN)6](俗名:赤血盐)中。铁与环戊二烯的化合物二茂铁,是一种具有夹心结构的金属有机化合物。
铁的化学性质比较活泼,在一定条件下,可以跟多种非金属及某些化合物发生化学反应。
1、铁跟氧气的反应
①铁丝在氧气中点燃:3Fe+2O2Fe3O4
现象:剧烈燃烧,火星四射,放出大量的热,生成黑色固体。
②铁的生锈
下列实验分别静置一周
现象:①、②号试管中的铁钉未生锈;③号试管中铁钉生锈,且在水与空气的交界面处,铁锈最多。
结论:铁在干燥的空气中不易生锈,在潮湿的空气中易生锈。
铁生锈的过程是铁与氧气和水发生的一系列的复杂的化学反应,在此我们不做过多的讨论,只需知道,铁生锈是自发的氧化反应,条件是与O2和H2O接触,铁锈的主要成分是Fe2O3。
一\单质有还原性,体现在与非金属氧化物,和酸(包括氧化性酸),还有金属活动顺序排在铁后的高价金属态离子或氧化物:
二\中间价态的铁既可以表现还原性,也可以表现氧化性,(依据金属活动顺序表和化学元素表的相关规律
三\最高价的铁即+3价,主要体现氧化性,是一种常见的氧化物
相对原子质量55.847。铁有多种同素异形体,
如α铁、β铁、γ铁、б铁等。Fe铁是比较活泼的金属,在金属活动顺序表里排在氢的前面。常温时,铁在干燥的空气里不易与氧、硫、氯等非金属单质起反应,在高温时,则剧烈反应。
化合价分+2 +3 分别是亚铁 铁,氧气中燃烧火光四射,生成Fe3O4
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