推荐回答(4个)
NaH我们通常当成是离子化合物,因为它具有离子化合物的特点(熔点高、熔融状态可以导电),但是它不是典型的离子化合物。一般只有卤素和碱金属组成的化合物才是典型的离子化合物。
氢与其他元素形成的二元化合物。但一般科学技术工作中总是把氢同金属的二元化合物称氢化物,而把氢同非金属的二元化合物称某化氢。在周期表中,除稀有气体外的元素几乎都可以和氢形成氢化物,大体分为离子型、共价型和过渡型3类,它们的性质各不相同。
1.离子型氢化物也称盐型氢化物。是氢和碱金属、碱土金属中的钙、锶、钡、镭所形成的二元化合物。其固体为离子晶体,如NaH、BaH2等。这些元素的电负性都比氢的电负性小。在这类氢化物中,氢以H-形式存在,熔融态能导电,电解时在阳极放出氢气。离子型氢化物中氢的氧化数为-1,具有强烈失电子趋势,是很强的还原剂,在水溶液中与水强烈反应放出氢气,使溶液呈强碱性,如:
CaH2+2H2O→Ca(OH)2+2H2↑
在高温下还原性更强,如:
NaH+2CO→HCOONa+C
2CaH2+PbSO4→PbS+2Ca(OH)2
2LiH+TiO2→Ti+2LiOH
离子型氢化物可由金属与氢气在不同条件下直接合成制得。除用做还原剂外,还用做干燥剂、脱水剂、氢气发生剂,1kg氢化锂在标准状态下同水反应可以产生2.8m3的氢气。在非水溶剂中与+Ⅲ氧化态的B(Ⅲ),Al(Ⅲ)等生成广泛用于有机合成和无机合成的复合氢化物,如氢化铝锂:
4LiH+AlCl3LiAlH4+3LiCl
复合氢化物主要用做还原剂、引发剂和催化剂。
2.共价型氢化物也称分子型氢化物。由氢和ⅢA~ⅦA族元素所形成。其中与ⅢA族元素形成的氢化物是缺电子化合物和聚合型氢化物,如乙硼烷B2H6,氢化铝(AlH3)n等。各共价型氢化物热稳定性相差十分悬殊,氢化铅PbH4,氢化铋BiH3在室温下强烈分解,氟化氢,水受热到1000℃时也几乎不分解。共价型氢化物也有还原性,因氢的氧化数为+1,其还原性大小取决于另一元素R-n失电子能力。一般说,同一族从上至下还原性增强,同一周期从左至右还原性减弱,例如:
4NH3+5O24NO+6H2O
2PH3+4O2P2O5+3H2O
2H2S+3O22SO2+2H2O
共价型氢化物在水中的行为较为复杂。常见为:
形成强酸的:HCl,HBr,HI;
形成弱酸的:HF,H2S,H2Se,H2Te;
形成碱的:NH3;
水解放出氢气的:B2H6,SiH4;
与水不作用的:CH4,PH3,AsH3,GeH4,SnH4,SbH3。
氢化物RHn给出质子的能力一般与R的电负性、半径有关。同一周期从左至右酸性随R的电负性增大而增强;同一族,从上至下,酸性增强主要由R的半径相应增大决定。酸碱性强弱由氢化物在水中电离出H+质子的热化学循环过程中总能量效应决定。
3.过渡型氢化物也称金属型氢化物。是除上述两类外,其余元素与氢形成的二元化合物,这类氢化物组成不符合正常化合价规律,如,氢化镧LaH2.76,氢化铈CeH2.69,氢化钯Pd2H等。它们晶格中金属原子的排列基本上保持不变,只是相邻原子间距离稍有增加。因氢原子占据金属晶格中的空隙位置,也称间充型氢化物。过渡型氢化物的形成与金属本性、温度以及氢气分压有关。它们的性质与母体金属性质非常相似,并具有明显的强还原性。一般热稳定性差,受热后易放出氢气。氢气作为未来很有希望的能源,要解决的中心问题是如何储存。一些金属或合金是储氢的好材料。钯、钯合金及铀都是强吸氢材料,但价格昂贵。近年来,最受人们注意的是镧镍-5LaNi5(吸氢后为LaNi5H6),它是一种储氢的好材料。容量为7L的小钢瓶内装镧镍-5所能盛的氢气(304kPa),相当于容量为40L的15000kPa高压氢气钢瓶所容纳的氢气(重量相当),只要略微加热,LaNi5H6即可把储存的全部氢气释放出来。除镧镍-5外,La-Ni-Cu,Zr-Al-Ni,Ti-Fe等吸氢材料也正在研究中。研究中国的丰产元素,尤其是稀土金属及其合金的吸氢作用有着更重要的意义。
单纯从电负性差值判断不是离子化合物
很多无机教材都认为是离子型为主
至于NH4H是中学老师杜撰的化合物。
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